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Molecular alignment during gel formation from methyl methacrylate: An excimer fluorescence study
(Taylor & Francis Ltd, 2005-05)
Glass transition during bulk polymerization was studied in free-radical cross-linking copolymerization (FCC) of methyl methacrylate (MMA) using the steady-state fluorescence (SSF) technique. Naphthalene (N) was used as a ...
Small molecule desorption prior to dissolution of a polymeric glass
(Wiley Subscription Services, Inc., A Wiley Company, 2006-07-15)
Poly(methyl methacrylate) (PMMA) discs in various molecular weights (M-w) were prepared by free-radical polymerization. Pyrene (Py) was introduced during polymerization as a fluorescence probe. In situ steady state ...