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Determination of pre-gelation and post-gelation activation energies during free radical crosslinking copolymerization
(Taylor & Francis Ltd, 2005)
Steady-state fluorescence (SSF) and dilatoraetric techniques were used to study the free-radical crosslinking copolymerization (FCC) of styrene (S) and divinylbenzene (DVB) in bulk. The gel points (t g) were recorded by ...
Comparision of critical parameters of polymerization and gelation processes: A fast transient fluorescence study
(World Scientific Publ Co Pte Ltd, 2005-03-10)
The fast transient fluorescence technique was used to study free-radical polymerization and crosslinking copolymerization of styrene. Ethylene glycol dimethacrylate and Pyrene were used as crosslinking agent and fluorescence ...
Universal behaviour of glass transition exponents in various polymeric systems
(VSP BV, Brill Academic Publishers, 2005)
The fast transient fluorescence (FTRF) technique was used to study the critical exponents during glass transition in free-radical cross-linking copolymerization (FCC). Methyl methacrylate (MMA), ethyl methacrylate (EMA) ...
Molecular alignment during gel formation from methyl methacrylate: An excimer fluorescence study
(Taylor & Francis Ltd, 2005-05)
Glass transition during bulk polymerization was studied in free-radical cross-linking copolymerization (FCC) of methyl methacrylate (MMA) using the steady-state fluorescence (SSF) technique. Naphthalene (N) was used as a ...
Universal behaviour of gel formation from acrylamide-carrageenan mixture around the gel point: A fluorescence study
(Taylor & Francis Group, 2006-08)
The steady state fluorescence (SSF) technique was used to study the sol-gel transition, for the solution free radical crosslinking copolymerization of acrylamide (AAm) with various carrageenan content. N, N'- methylenebis ...
Study on critical behaviour in N-isopropyl acrylamide gels by using fluorescence technique
(Taylor & Francis Group, 2006-11)
The steady state fluorescence (SSF) technique was used to study the sol-gel transition for the solution free radical crosslinking copolymerization of N-isopropyl acrylamide (NIPA), with N,N'-methylenebis (acrylamide) (BIS) ...
Study on swelling of hydrogels (PAAm) at various temperatures by using fluorescence technique
(Springer US, 2007-10)
Steady-state fluorescence (SSF) technique was employed for studying swelling of polyacrylamide (PAAm) hydrogels. Disc-shaped gels were prepared by free-radical crosslinking copolymerization of acrylamide (AAm) with N, N'- ...
