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Yayın Vapor-induced film formation from low-T-g particles for different solvent compositions(Elsevier Inc, 2006-05-15) Arda, Ertan; Kara, Selim; Saraç, Ayfer; Pekcan, Mehmet ÖnderThe photon transmission method was used to study latex film formation from poly(vinyl acetate) (PVAc) particles induced by two different solvents. Films with the same latex content were prepared from PVAc particles and exposed to vapor of ethanol-water and acetone-water mixtures in various compositions. Transmitted photon intensities, I-tr, from these films increased with increasing vapor exposure time. The increase in I-tr is attributed to the increase in crossing density at the polymer-polymer junction. The Prager-Tirrell model was employed to obtain the back-and-forth frequency, v, of the reptating polymer chain during film formation induced by solvent vapor. It was observed that the produced v values increase as the solvent content is increased for both solvents. Abilities of both solvents to form films were interpreted with the solubility parameters of the solvents and the PVAc.Yayın Film formation stages for poly(vinyl acetate) latex particles: a photon transmission study(Springer-Verlag, 2006-07) Kara, Selim; Pekcan, Mehmet Önder; Saraç, Ayfer; Arda, ErtanPhoton transmission technique was used to monitor the evolution of transparency during film formation from poly(vinyl acetate) (PVAc) latex particles. The latex films were prepared below the glass transition temperature (T-g) of PVAc. These films were annealed at elevated temperatures in various time intervals above the T-g of PVAc. It is observed that transmitted photon intensity (I-tr) from these films increased as the annealing temperature is increased. It is seen from I (tr) curves that there are two film formation stages. These successive stages are named void closure (viscous flow) and interdiffusion. The activation energies for viscous flow (Delta H) and backbone motion (Delta E (b)) were obtained by using well-defined models. The averaged values of the backbone (Delta E (b)) and the viscous flow activation energies (Delta H) were found to be 188.6 and 5.6 kcal/mol, respectively. The minimum film formation (tau (M),T (M)) and healing points (tau (H),T (H)) were determined. Minimum film formation (Delta E (M)) and healing activation energies (Delta E (H)) were measured using these time-temperature pairs. Delta E (M) and Delta E (H) were found to be 32.5 and 28.3 kcal/mol, respectively.
