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Yayın Reversible film formation from PS doped PNIPAM particles in various compositions(John Wiley & Sons Inc, 2008-02) Uğur, Şaziye; Yargı, Önder; Pekcan, Mehmet ÖnderFilm formation from polystyrene (PS) doped poly(N-isopropylacrylamide) (PNIPAM) particles was studied using photon transmission technique. The transmitted light intensity, Itr, was monitored during film formation process. Films were prepared by mixing PS and PNIPAM particles in various compositions ranging from 5 to 50 %. Samples were separately heated and cooled in constant rate at temperatures ranging from 10 to 100 C. The increase and decrease in Itr during heating-cooling cycles were explained by void closure and void reconstruction processes. The corresponding activation energies were measured during the reversible film formation process. Percolation model was used to interpret the distribution of PS particles in PNIPAM lattice.Yayın Film formation from PS latex doped PNIPAM hydrogels at various heating and cooling rates(VSP BV, Brill Academic Publishers, 2008-05-01) Uğur, Şaziye; Yargı, Önder; Pekcan, Mehmet ÖnderFilm formation from polystrene (PS) latex doped poly(N-isopropylacrylamide) (PNIPAM) hydrogels was studied by using photon transmission technique. The transmitted light intensity, It, was monitored during film formation process. Films were prepared by annealing, 10 wt% PS doped PNIPAM particles at five different heating and cooling rates at temperatures ranging from 10 to 100 degrees C. I-tr presented a hysteresis loops during heating-cooling cycles, which were explained by void closure and void reconstruction processes. The corresponding activation energies were measured during reversible film formation process. Void closure and void reconstruction models were introduced to produce the activation energies.












