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Yayın Film formation from TiO2-polystyrene latex composite: a fluorescence study(Taylor & Francis Group, 2007-03-01) Uğur, Şaziye; Sunay Yapışkan, Münüre Selin; Tepehan, Fatma Zehra; Pekcan, Mehmet ÖnderThis work reports the use of the steady state fluorescence (SSF) technique for studying film formation from TiO2 covered polystyrene (PS) latex particles. The composite films were prepared from pyrene (P)-labeled PS particles by covering them with TiO2 at room temperature and then annealed at elevated temperatures in 10 min time interval above glass transition (T-g) temperature of polystyrene. Five different composite films were studied in various TiO2 layer contents. Fluorescence intensities Ip from P were measured after each annealing step to monitor the stages of film formation. Films showed considerable increase in Ip above the certain onset temperature called minimum film forming temperature, T-0. Void closure and interdiffusion stages were modeled and related activation energies were determined and found to be 23.12 and 92.80 kJ mol(-1), respectively.Yayın A path loss model for link budget analysis of indoor visible light communications(Istanbul Univ-Cerrahpasa, 2021-05) Miramirkhani, FarshadIn the context of beyond 5G indoor communication systems, visible light communications (VLC) has emerged as a viable supplement for existing radio frequency based systems and as an enabler for high data rate communications. However, the existing indoor VLC systems are limited by detrimental outages caused by fluctuations in the VLC channel gain because of user mobility. In this study, we proposed a tractable path loss model for indoor VLC that reflects the effect of room size and coating material of surfaces. We performed an extensive advanced ray tracing simulation to obtain the channel impulse responses within a room and presented a path loss model as a function of distance, room size, and coating material through curve fitting. In addition, path loss parameters such as the path loss exponent and the standard deviation of the shadowing component were determined. The simulation results indicate that path loss is a linear function of distance, path loss exponent is a function of room size and coating material, and shadowing follows a log normal distribution.Yayın Surface modification of titanium using BSA-Loaded chitosan and chitosan/gelatin polymers(Springer Berlin Heidelberg, 2016-10) Önder, SakipThe integration of titanium-based implants with the surrounding bone tissue needs to be improved to increase their service life. This work presents a surface modification technique to increase the osteointegration of titanium implants. The studies were conducted in three main steps: (i) surface modification of titanium using bovine serum albumin (BSA)-loaded chitosan and chitosan/gelatin polymers, (ii) studies of BSA release from these surfaces, (iii) effect of porosity and polymer composition on osteoblast cell proliferation. TiO2 and COOH groups were formed on titanium surfaces. Then, chitosan and chitosan (C)/gelatin (G) with various ratios (G:C = 0.5:1, 1:1, 1:0.5) were mixed with BSA and fixed to the surface via carbodiimide chemistry (EDC/NHS). After the immobilization process, samples were exposed to either air or freeze-drying. Characterization studies were conducted using Fourier transform-infrared spectroscopy and scanning electron microscopy. Finally, BSA release studies in phosphate-buffered saline (0.1 M, 37 °C) and cell (osteoblast) proliferation studies using MTS assay were conducted. BSA-loaded porous structures were obtained on chitosan- and chitosan/gelatin-containing surfaces after freeze-drying, while smooth surfaces were obtained after air-drying. The BSA release rate was directly correlated with increasing gelatin amount in the chitosan/gelatin coatings. MTS analysis was not conclusive because of the absorption properties of polymer coatings. However, absorbed color density in chitosan/gelatin (G:C = 1:1) polymers under freeze-drying conditions was more dominant, indicating better cell proliferation. This method may be used to release growth factors for controlled cell proliferation and differentiation or for the local delivery of antimicrobial drugs to prevent contamination during implementation in hard tissue applications.Yayın Coordination in building an observatory: A case study of Eastern Anatolian Observatory (DAG)(SPIE-Int Soc Optical Engineering, 2018) Şahmalı, Ali Erkan; Yeşilyaprak, Cahit; Keskin, OnurEastern Anatolian Observatory (DAG) is designed to build on one of the summits of Palandoken Mountains in Erzurum, Turkey, at an altitude of 3,151 meters. The building is under construction since 2015 and expected to be completed in 2020. The building is designed as an integrated building, having operational departments, services, mechanical and electrical infrastructure for observations as well as cleaning and coating units, adjacent to the main observatory building. As one might expect this integration creates serious coordination problems between architect, engineers, telescope, enclosure, and cleaning & coating unit manufacturers. The construction progress of the investment is almost 20%. There are quite an amount of "lessons learned" in this period, and need to be developed by the parties, for their existing and future works. The building has so many challenges such as geological and geographical limitations, environmental and meteorological constraints, engineering and structural considerations, energy efficiency and sustainability, materials used and their performances at these limitations.Yayın Effect of magnesium and osteoblast cell presence on hydroxyapatite formation on (Ti,Mg)N thin film coatings(Springer, 2016-07-19) Önder, Sakip; Çalıkoğlu Koyuncu, Ayşe Ceren Eren; Köse, Gamze Torun; Kazmanlı, Kürşat Muhammet; Kök, Fatma Neşe; Ürgen, MustafaTiN and (Ti,Mg)N thin film coatings were deposited on Ti substrates by an arc-physical vapor deposition technique. The effect of cell presence on hydroxyapatite (HA) formation was investigated using surfaces with four different Mg contents (0, 8.1, 11.31, and 28.49 at.%). Accelerated corrosion above 10 at.% Mg had a negative effect on the performance in terms of both cell proliferation and mineralization. In the absence of cells, Mg-free TiN coatings and low-Mg (8.1 at.%)-doped (Ti,Mg)N surfaces led to an early HA deposition (after 7 days and 14 days, respectively) in cell culture medium (DMEM), but the crystallinity was low. More crystalline HA structures were obtained in the presence of the cells. HA deposits with an ideal Ca/P ratio were obtained at least a week earlier, at day 14, in TiN and low-Mg (8.1 at.%)-doped (Ti,Mg)N compared with that of high-Mg-containing surfaces (>10 at.%). A thicker mineralized matrix was formed on low-Mg (8.1 at.%)-doped (Ti,Mg)N relative to that of the TiN sample. Low-Mg doping (<10 at.%) into TiN coatings resulted in better cell proliferation and thicker mineralized matrix formation, so it could be a promising alternative for hard tissue applications.Yayın Fluorescence study on Al2O3-polystyrene latex composite film formation(John Wiley & Sons Inc, 2005-06) Uğur, Şaziye; Salman, Oğuz Umut; Tepehan, Galip Gültekin; Tepehan, Fatma Zehra; Pekcan, Mehmet ÖnderThis work reports a steady state fluorescence (SSF) technique for studying film formation from mixture of Al2O3 and polystyrene (PS) latex particles. The composite films were prepared from dispersion of pyrene (P)labeled PS particles in Al2O3 solution at room temperature and annealed at elevated temperatures in 10-min time interval above glass transition (T-g) temperature of polystyrene. Nine different composites film were studied in various latex contents. Fluorescence intensities (I-P) from P were measured after each annealing step to monitor the stages of film formation. No variations in I-p were detected for the films prepared with higher than 33 wt% Al2O3 content. However films prepared below 33 wt% Al2O3 content show considerable increase in I-P above the certain onset temperature called minimum film forming temperature, To. Healing temperatures T., were determined from the maxima of I-P. Void closure and interdiffusion stages were modeled and related activation energies were determined and found to be 20 and 97 kJ.mol(-1), respectively.Yayın Ceramic encapsulated latex composites(Elsevier Inc, 2006-04-15) Uğur, Şaziye; Pehlivan, Esat; Tepehan, Fatma Zehra; Pekcan, Mehmet ÖnderThis work reports the encapsulation of latex particles in Al(2)O(3)-polystyrene (PS) composite films. These films were prepared from PS particles in Al(2)O(3) dispersion at room temperature in various latex contents. Composite films were annealed at elevated temperatures in 10 min time interval above the glass transition temperature (T,,) of polystyrene. Transmitted photon intensities. I(tr) were monitored after each annealing step. AFM micrographs were also used to observe the physical changes of the composite films during annealing. It was observed that latex particles are encapsulated above a critical Al(2)O(3) content of 33 wt% which corresponds to the critical occupation probability of p(c) = 0.33 at which the film obey the site-percolation model with a critical exponent of 0.45. Below pc it was seen that complete latex film formation process took place, where transparency of the film was increased by annealing.Yayın Transient multi-domain thermal modeling of interrupted cutting with coated tools(Springer Science and Business Media Deutschland GmbH, 2021-09) Karagüzel, UmutInterrupted cutting operations, such as milling, produce fluctuating tool temperatures which directly affect the process outputs. Thus, prediction of cutting tool temperatures enables process planning, selection of materials for tool substrate and coating layers, and tool geometric design for improved productivity in machining operations. Theoretical analysis of temperature is a cost effective way to predict the tool temperatures. Considering the industrial needs, a theoretical model should be fast, easy to implement, and reliable. To that end, a novel hybrid model, which assembles analytical and numerical methods, is proposed in this study. This novel transient thermal model simulates the interrupted cutting with coated cutting tools. The proposed model includes an analytical heat flux calculation at the tool-chip interface considering the sticking-sliding contact behavior. The determined heat flux is, then, used to perform a numerical solution of the transient heat conduction problem in the cutting tool geometry with temperature-dependent thermal properties. The developed model is validated with experimental results found in literature under different cutting conditions. The results show that the model can predict the maximum temperatures generated in a thermal cycle with an accuracy of 2–10%. Thus, the proposed model can be further used to determine the process parameters, properties of coating layers, and tool geometric design.
