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Yayın Fluorescence study on Al2O3-polystyrene latex composite film formation(John Wiley & Sons Inc, 2005-06) Uğur, Şaziye; Salman, Oğuz Umut; Tepehan, Galip Gültekin; Tepehan, Fatma Zehra; Pekcan, Mehmet ÖnderThis work reports a steady state fluorescence (SSF) technique for studying film formation from mixture of Al2O3 and polystyrene (PS) latex particles. The composite films were prepared from dispersion of pyrene (P)labeled PS particles in Al2O3 solution at room temperature and annealed at elevated temperatures in 10-min time interval above glass transition (T-g) temperature of polystyrene. Nine different composites film were studied in various latex contents. Fluorescence intensities (I-P) from P were measured after each annealing step to monitor the stages of film formation. No variations in I-p were detected for the films prepared with higher than 33 wt% Al2O3 content. However films prepared below 33 wt% Al2O3 content show considerable increase in I-P above the certain onset temperature called minimum film forming temperature, To. Healing temperatures T., were determined from the maxima of I-P. Void closure and interdiffusion stages were modeled and related activation energies were determined and found to be 20 and 97 kJ.mol(-1), respectively.Yayın Ceramic encapsulated latex composites(Elsevier Inc, 2006-04-15) Uğur, Şaziye; Pehlivan, Esat; Tepehan, Fatma Zehra; Pekcan, Mehmet ÖnderThis work reports the encapsulation of latex particles in Al(2)O(3)-polystyrene (PS) composite films. These films were prepared from PS particles in Al(2)O(3) dispersion at room temperature in various latex contents. Composite films were annealed at elevated temperatures in 10 min time interval above the glass transition temperature (T,,) of polystyrene. Transmitted photon intensities. I(tr) were monitored after each annealing step. AFM micrographs were also used to observe the physical changes of the composite films during annealing. It was observed that latex particles are encapsulated above a critical Al(2)O(3) content of 33 wt% which corresponds to the critical occupation probability of p(c) = 0.33 at which the film obey the site-percolation model with a critical exponent of 0.45. Below pc it was seen that complete latex film formation process took place, where transparency of the film was increased by annealing.Yayın Transient multi-domain thermal modeling of interrupted cutting with coated tools(Springer Science and Business Media Deutschland GmbH, 2021-09) Karagüzel, UmutInterrupted cutting operations, such as milling, produce fluctuating tool temperatures which directly affect the process outputs. Thus, prediction of cutting tool temperatures enables process planning, selection of materials for tool substrate and coating layers, and tool geometric design for improved productivity in machining operations. Theoretical analysis of temperature is a cost effective way to predict the tool temperatures. Considering the industrial needs, a theoretical model should be fast, easy to implement, and reliable. To that end, a novel hybrid model, which assembles analytical and numerical methods, is proposed in this study. This novel transient thermal model simulates the interrupted cutting with coated cutting tools. The proposed model includes an analytical heat flux calculation at the tool-chip interface considering the sticking-sliding contact behavior. The determined heat flux is, then, used to perform a numerical solution of the transient heat conduction problem in the cutting tool geometry with temperature-dependent thermal properties. The developed model is validated with experimental results found in literature under different cutting conditions. The results show that the model can predict the maximum temperatures generated in a thermal cycle with an accuracy of 2–10%. Thus, the proposed model can be further used to determine the process parameters, properties of coating layers, and tool geometric design.
