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Yayın Theory of fluidity of liquids, glass transition, and melting(Elsevier B.V., 2006-03-01) Dimitrov, Ventzislav IvanovThis is a presentation of a rigorous theory of fluidity of liquids, glass transition and melting of solids in the frame of an asymmetric double well potential model. Potential wells are doubled time to time by the local density fluctuations caused by the thermal longitudinal waves. The average frequency of doubling of potential wells is equal to the frequency of the most energetic waves which obey a law similar to Wein's displacement law in black body radiation. Based on the equilibrium thermodynamic theory of fluctuations and the displacement law, a law of linear pre-diffusion mean-square displacement of particles in a solid is derived: the mean-square displacement of molecules within their potential wells increases linearly with temperature. It is shown that when this is broken-down (where the mean-square displacement at a certain temperature rapidly changes its slope as a function of temperature) glass devitrifies and crystal melts, and all possible solid-liquid transitions of a substance occur at the same critical mean-square displacement: any solid (not only crystals) transforms into liquid when the mean-square displacement, as a fraction of the average intermolecular distance, acquires a certain universal critical value - the same for different substances. It is proved that molecules in a liquid perform specific Brownian motion. The average jump distance is a function of temperature and it is much smaller than the nearest intermolecular distances. At a certain temperature, shown to be the Kauzmann temperature, the average jump distance of Brownian motion becomes equal to zero: the supercooled liquid undergoes glass transition. The transition was proven to be a phase transition of the fourth order: the free energy of the system and its first, second and third derivatives are all continuous functions, but its fourth derivative with respect to temperature is discontinuous. Molecular mobility, diffusion and viscosity are obtained as functions of temperature.Yayın Effect of mechanically exfoliated graphite flakes on morphological, mechanical, and thermal properties of epoxy(Multidisciplinary Digital Publishing Institute (MDPI), 2024-11-11) Gül, Ayşenur; Kamali, Ali RezaCarbon-reinforced polymer composites form an important category of advanced materials, and there is an increasing demand to enhance their performance using more convenient and scalable processes at low costs. In the present study, graphitic flakes were prepared by the mechanical exfoliation of synthetic graphite electrodes and utilized as an abundant and potentially low-cost filler to fabricate epoxy-based composites with different additive ratios of 1–10 wt.%. The morphological, structural, thermal, and mechanical properties of these composites were investigated. It was found that the thermal conductivity of the composites increases by adding graphite, and this increase mainly depends on the ratio of the graphite additive. The addition of graphite was found to have a diverse effect on the mechanical properties of the composites: the tensile strength of the composites decreases with the addition of graphite, whilst their compressive strength and elastic modulus are enhanced. The results demonstrate that incorporating 5 wt% of commercially available graphite into epoxy not only raises the thermal conductivity of the material from 0.223 to 0.485 W/m·K, but also enhances its compressive strength from 66 MPa to 72 MPa. The diverse influence of graphite provides opportunities to prepare epoxy composites with desirable properties for different applications.Yayın Enhancement of epoxy properties through graphene nanofillers produced in molten salt: morphological, thermal and mechanical characterization(Springer, 2026) Gül, Ayşenur; Kamali, Ali RezaThis research investigates the enhancement of epoxy resin properties through the incorporation of graphene nanoplatelets (GNPs), synthesized via the molten salt exfoliation method, as nanofillers. The study evaluates the morphology, thermal conductivity, and mechanical performance of the resulting nanocomposites. Electron microscopy reveals a high density of reactive edge sites in the graphene material, which enable bonding with epoxy groups during curing. It also shows a uniform dispersion of graphene nanoplatelets (GNPs) within the epoxy matrix, leading to reduced void formation and enhanced interfacial bonding. A notable improvement in the physical and mechanical properties of the epoxy was observed with the addition of GNPs up to 1.0 wt%. At this concentration, Young’s modulus increased by approximately 42% (from 2.9 to 4.2 GPa), while thermal conductivity, compressive strength, and tensile strength improved by around 41%, 9%, and 32%, respectively. These findings indicate that the integration of GNPs into epoxy resin significantly enhances both thermal and mechanical performance, positioning the nanocomposites as strong candidates for advanced structural applications.
